For sure! My community is served by a volunteer department and I joined a couple years ago, definitely a rewarding experience. Now not only have I gotten to sit in a truck, but I drive them, have learned all sorts of cool tools like the jaws of life and get to work with a great group of people serving our community.
You don't need to be young and fit either (I'm not!), there's a job for everyone. Anyone who's interested should definitely check out their local department. Most have active Facebook pages sharing updates and their website should have info on how to learn more about joining.
I'm not sure where that number came from but according to Wikipedia the conversion from momentum to electricity loses 10-20% and the conversion from electricity to battery storage is another 10-20% leaving a theoretical recovery at 60-70%. In real world tests, Teslas recovered 20-32% range with regenerative braking, a far cry from 2-5% you cite. https://electrek.co/2018/04/24/regenerative-braking-how-it-works/