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I think you're disregarding the fact that the idea that breathing will kill you, while you are tied down with a mask over your face, would likely lead to more than a couple terrifying moments of holding your breath and holding on to life for as long as you can.
Nitrogen asphyxiation as a suicide method is painless as far as we know, yes. But try holding your breath for as long as you can, and imagine you are tied down and will die shortly after your next breath... doesn't exactly sound quick or peaceful to me.
I'm not forgetting that aspect of things, as horrible as they are. But they are a significant improvement from the pain and suffering caused by lethal injections. If I were on death row I would beg for nitrogen over lethal injection. The people administering injections often receive no training and screw it up often enough for it to not be a viable method in my eyes. Additionally, the compounds they use cause a burning sensation in your veins. Throughout your entire body. Id rather panic and pass out for a minute than be set on fire from the inside for several minutes until my lungs fill with fluid enough for me to pass out from pain and suffocation that's more akin to drowning or strangulation than regular ole hypoxia.
I don't think it's necessarily peaceful, but it is quicker and less painful and that's about all we can ask for if we're going to be executing people.
To be fair, lethal injections also sound absolutely horrible (and for the record I agree fully that nobody should be executing anybody in the first place).
Still, to me it sounds so absolutely terrifying to be in a situation where I know that my next breath will be my last, and having nothing but willpower to stay alive for however long I can. It sounds quite similar to torturing someone while leaving them a gun so they can end it when they can't take anymore.
At least with other methods you aren't forced to pull the figurative trigger yourself.
To me it really just underlines how barbaric and inhumane these death penalties are...