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I'm not here to diss EVs or praise ICE vehicles, but I want to simply directly answer your question. There's one simple mantra that is applicable to a lot of things in life...the dose makes the poison. Not odd to see people extrapolate to that your scenario.
In one, although the quantity is greater, you're "diluting" the gas into the humongous atmosphere. In the other, you're taking the gas straight up undiluted.
They're saying a 300sqft garage is going to fill up with carbon monoxide long before the planet does because the volume of space is drastically different. It's why they tell you to spray paint in well ventilated areas versus huffing it out of a bag.