There is a place for graphically gorgeous distro's
As a current KDE user but extensive user of XFCE in the past, it may not come "pretty" out-of-the-box but XFCE can be a very aesthetically pleasing desktop environment. It can be configured just about every which way, and if I had to switch back to XFCE right now I could have things just about how I want them and be 100% as happy with my desktop as I am with KDE.
It's got defaults that just make sense, doesn't try to reinvent the wheel or the way we interact with our desktops, it's light and fast and reliable. It's associated default programs (Thunar, etc.) follow the same design paradigms and are a delight to use.
I Iove XFCE, and it will always have a special place in my heart.