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Fucking idiots. It's very difficult to make enough methanol to be dangerous with a standard mash and distilling methods. Most of the time these fucking idiots are using stolen methanol from industrial sites to bump up their ABV and they make people super sick with it. Stop killing/hospitalizing your customers and you won't get caught.
Dude ikr. You have to actively try to make methanol when you’re distilling, like only collecting the foreshots over and over.
And by that point I’d be super easy to tell it’s not regular alcohol because it will smell like nail polish remover and other volatile compounds.
There's actually more methanol in the tails than the foreshots due to complicated chemistry.
Can you elaborate or link to further reading?
I assumed methanol is the first to go because of its lower boiling point — 65 degrees compared to ethanol at 78
this explains it a bit. The quick and dirty answer is that when you boil a mash, you are boiling a solution, not just 3 individual liquids (ignoring all the other stuff in there). It's similar to how adding salt to water lowers the freezing point and raises the boiling point.
Water is polar, while ethanol only has mild polarity. Methanol is more polar than ethanol, so it holds onto the water more. If you had a mixture of methanol and ethanol with no water, you'd probably get more methanol first, but the water changes things.